When you think of famous Hollywood love triangles, Jennifer Aniston, Brad Pitt, and Angelina Jolie might be the first trio to come to mind. After months of whispers from the set of Mr. & Mrs. Smith, the buzz around co-stars Pitt and Jolie was hard to ignore. But then, Aniston and her husband suddenly went on a holiday vacation in the Caribbean, and all felt right with the world. But as the story goes, Pitt finally confessed his true feelings for Jolie on that trip — and they announced their split on Jan. 7, 2005.